Sulfonated poly(phthalazinone ether ketone) for proton exchange membranes in direct methanol fuel cells
نویسندگان
چکیده
منابع مشابه
An overview of organic/inorganic membranes based on sulfonated poly ether ether ketone for application in proton exchange membrane fuel cells
Nowadays, proton exchange membrane fuel cells (PEMFCs) are the most promising green energy conversion devices for portable and stationary applications. Traditionally, these devices were based onperfluoro-sulfonic acid electrolytes membranes, given the commercial name Nafion. Nafion is the mostused electrolyte membrane till now; because of its high electrochemical properties su...
متن کاملRecent advances in sulfonated poly ( ether ether ketone ) based proton exchange membranes for high temperature fuel cells
Proton exchange membranes (PEMs) play an important role in the fuel cell systems. A good PEM must meet a series of requirements such as high proton conductivity, excellent mechanical strength and stability, chemical and electrochemical stability, low fuel crossover, etc. Nafion is currently the most commercially utilized electrolyte membranes for polymer electrolyte fuel cells, with high chemic...
متن کاملCharacterization of Polyethylene-Graft-Sulfonated Polyarylsulfone Proton Exchange Membranes for Direct Methanol Fuel Cell Applications
This paper examines polymer film morphology and several important properties of polyethylene-graft-sulfonated polyarylene ether sulfone (PE-g-s-PAES) proton exchange membranes (PEMs) for direct methanol fuel cell applications. Due to the extreme surface energy differences between a semi-crystalline and hydrophobic PE backbone and several amorphous and hydrophilic s-PAES side chains, the PE-g-s-...
متن کاملA new interpretation of SAXS peaks in sulfonated poly(ether ether ketone) (sPEEK) membranes for fuel cells.
The structure of a commercial sulfonated poly(ether ether ketone) (sPEEK) membrane was analyzed by Small-Angle X-Ray Scattering (SAXS) for different water uptakes obtained after immersion in liquid water at various temperatures. For low membrane swelling, the SAXS profile displays only a wide-angle peak in the 0.2-0.3 Å(-1) region. As the membrane swells, two supplementary correlation peaks ari...
متن کاملA new supramolecular sulfonated polyimide for use in proton exchange membranes for fuel cells.
Uracil-terminated telechelic sulfonated polyimides (SPI-U) were transformed into noncovalent network membranes through biocomplementary hydrogen bonding recognition in the presence of an adenine-based crosslinking agent. SPI-U membrane exhibited dramatically improved methanol permeability, oxidative stability, proton conductivity, and selectivity relative to those of the standard SPI.
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ژورنال
عنوان ژورنال: Journal of Membrane Science
سال: 2005
ISSN: 0376-7388
DOI: 10.1016/j.memsci.2005.04.052